There were some slight changes to the planned content, the biggest being me realizing that (a) I really, really didn’t want to reread Fallout: Equestria and (b) there wasn’t anything to say about it I hadn’t already said about Background Pony and “Rainbow Factory,” so I dropped it and went with two commenter suggestions instead of just one.
The complete TOC (subject to change, but I doubt it’ll change very much):

• Part One: The Show
  1. I’ve finally figured out why you’re having so much trouble being liked! (The Crystal Empire)
  2. Maybe something less over-the-top and not so super-hyper (Too Many Pinkie Pies)
  3. I’ll be embarrassed, shamed, disgraced, mortified, humiliated… (One Bad Apple)
  4. You will never have the amazing, show-stopping ability (Magic Duel)
  5. Actually, Twilight Sparkle, I’m the main singer tonight (Sleepless in Ponyville)
  6. The Wonderbolts will never let a loser like me join! (Wonderbolts Academy)
  7. Now hold on, everypony. We’ve done our best to improve supply this year. (Apple Family Reunion)
  8. That’s future Spike’s problem (Spike at Your Service)
  9. Sometimes it can be hard for a shy pony like me to stand up for myself (Keep Calm and Flutter On)
  10. SPIKE WANT! (Just for Sidekicks)
  11. I’m bored. (Games Ponies Play)
  12. Princess Celestia Is Best Pony
  13. I don’t know when she changed, but she changed! (Magical Mystery Cure)
  14. I wonder where I’m going now/What my role is meant to be/I don’t know how to travel/To a future that I can’t see (Magical Mystery Cure)
• Part Two: Derivative Works
  1. Alchemical Fandom: A Case Study in Doctor Whooves (Adapted from my guest post for TARDIS Eruditorum, reprinted with permission)
  2. Last Survivor of Gallopfrey (Time Lords and Terror)
  3. Save Derpy (Doctor Whooves and Assistant)
  4. Fire the Orbital Friendship Beam (Double Rainboom)
  5. [Pony] Is My Waifu (Snowdrop)
  6. Welcome to the Herd (Friendship Is Dragons)
  7. Confound These Ponies (Friendship Is Witchcraft)
  8. Haters gonna hate (My Little Po-Mo: Unauthorized Critical Essays on My Little Pony: Friendship Is Magic Season One)
  9. The Glorious Lunar Republic (The Lunaverse, Season One)
  10. Princesses as Celebrities in Equestria
  11. Mods Are Asleep (The Return of Queen Crysalis Part 1-4)
  12. To the Mooooooooooooooooooon! (Nightmare Rarity, Parts 1-4)
  13. Big McIntosh is Best Pony
  14. Hit its weak point for massive damage (My Little Pony: Friendship Is Magic, Volumes 3 and 4)
  15. Solar Empire (Reflections, Parts 1-4)
  16. Hate Detected (Turnabout Storm)
  17. Ponify everything! (My Little Investigations Case 1: True Blue Scootaloo)
  18. Get Equipped With Magic (Mega Pony) (co-written with Frezno, who still needs to tell me how he wants to be credited)
  19. My favorite background pony is Applejack (Background Pony)
  20. Glorious pegasus master race (Rainbow Factory)
  21. Apples and apple accessories (Ask Jappleack/Pony.mov)
  22. RIP Golden Oak Library (The Elements of Harmony)
  23. From a feminist perspective, has MLP:FIM changed the world?
  24. Gak (Equestria Girls)
  25. I watch it for the plot (Equestria Girls: Rainbow Rocks)
• …Today I Learned… (Afterword)